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Weird! I’m running Bazzite kde (so fedora based, like Nobara but with different tweaks and it’s atomic), and gamescope gives me zero problems. Might be some weird combination of software versions between gamescope and kde in your system. Or just a general kde config problem. I love kde, but all that customization can absolutely come at the price of stability at times.
I have personal experience with BTRFS and Windows. And that experience is that it’s roughly as stable/complete as NTFS is for Linux. 6 of one and a half dozen the other. I can’t recommend either situation for guaranteed stability long term between systems if one really needs to swap between the OS’s frequently while accessing all the same files.