It looks like the radiator support for 360mm is limited to the top side. I also think the case was designed around vertical air cooled gpus or a custom cooling loop for the whole assembly. However I would honestly recommend against a water cooled gpu in this case. You’ve already got an AIO with the CPU, and an air cooled gpu in this set up will have no problem with airflow.
As for power, just get what you need and add like a 15/20% buffer minimum for the misc things like rgb or small fans. The rated TDP of all devices is available in their spec sheet.
Pi-hole, although really you can accomplish network ad blocking with just about any spare computer.JK refer to the comment below mine